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Accordingly, should leaf springs be painted?
Painting leaf springs is okay, lubing is not. Leaf springs have a damping factor as a result of the friction between the leaves, that's one reason there are no shocks in the rear on the deuce. Fewer leaves means less damping and shocks need to be added.
Keeping this in consideration, can I paint my shocks?
You can paint them, but keep in mind the shocks do get warm. Good prep with a good paint should do fine. For the boots, you can get new ones in your choice of color for under $5 ea and would hold up better than painting them. Yes, but keep in mind the new paint will chip off much easier than the factory coating.
To prepare your chassis, the first thing to do is gather your materials, which include: a PRE paint solution, electric sander, stripper or blaster, lint-free hand towels, and some epoxy primer. Using an epoxy primer will yield the best results when painting your chassis.