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Doc Martens, as a rule, are Secret Rain Boots. (They are also Secret Snow Boots, another important type of footwear.) If it rains, fine; if it doesn't, well, they're still the same cute pair of shoes you would wear on any other day.
Moreover, can you get Doc Martens wet?
Martens are sturdy shoes, they are however not water resistant. That being said, Dr. Martens do sell a fully waterproof boot, where you can be assured no water damage will be done. There are a few things you can do to protect your boots from water damage such as using the shoe protector to avoid unwanted wet patches.
Moreover, can you wear vegan Doc Martens in the rain?
Yes yes yes! I would highly recommend a pair. I got mine over a year ago and wear them out a ton in all sorts of weather (rain, snow, etc) and they are barely showing any signs of wear--a bit of creasing, no stretching though, and they still look pretty new.
You really don't have to do anything! Most recommend a water-protectant spray, which does work, but Dr. Martens are honestly very durable, and look even better with age/wear.